Molecular Probe Techniques in the Study of Colloidal Systems

نویسندگان

  • H. Caldararu
  • Agneta Caragheorgheopol
  • Marilena Vasilescu
  • Rodica Bandula
چکیده

This review presents some examples obtained by molecular techniques in the study of non-ionic reverse micelles of poly(ethylene oxide) type surfactants: tetraethylene glycol mono-ndodecyl ether (C12E4), Triton X-100, and triblok copolymers poly(ethylene oxide)-blockpoly(propylene oxide)-blockpoly(ethylene oxide) (L62 and L64 Pluronics). By using specific spectral parameters of spin, fluorescence and UV-VIS probes the microenvironment characteristics: polarity, viscosity and order degree in reverse micelle were investigated. The polarity data were expressed in a common scale, to be able to compare the results obtained using different spectroscopic methods. The aggregation number of the micelles has been obtained from time-resolved fluorescence quenching method.

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تاریخ انتشار 2008